Wetlands, including Peatlands

Challenges

PDK explores the feasibility of using NIRS as a rapid, cost-effective and field-based method for:

Summary of studies using NIRS for the analysis of peat

Photo of wetlandsIn a limited number of studies, NIRS has been shown to be feasible for the determination of bulk density, degree of humification, moisture content, and contents of several Sphagnum species, aggregate monocotyledons, and Ericales roots (McTiernan et al. 1998). Peat for industrial and domestic use has been analyzed for moisture and bulk density (Downey and Bryne 1986). Gross heat, C, cellulose, H, N, and ash were successfully determined in freeze-dried peat from Irish bogs (Beining et al. 2001). Anaerobic methane generation by methanogenic bacteria in peat was predicted by NIRS. Up to 84 % of the variance in methane production rates were explained using the NIR spectra (Nilsson et al. 1993). Recently, NIRS has been extended to pH, organic content, cation concentrations, total N, C and P, extracellular enzyme activity in wetland soils from western Florida (Cohen et al. 2005).

References on the analysis of wetlands by NIRS

Beining, B.A., N.M. Holden, S.M. Ward, and E.P. Farrell. 2001. The prediction of some peat properties for Irish industrial bogs using near infrared spectroscopy (unpublished). http://www.bnm.ie/downloads/beining.pdf

Cohen, M.J., J.P. Prenger and W.F. DeBusk. 2005. Visible – near infrared reflectance spectroscopy for rapid, nondestructive assessment of wetland soil quality. J. Environ. Quality 34: 1422-1434.

Downey, G., and P. Bryne. 1986. Prediction of moisture and bulk density in milled peat by near infrared reflectance. J. Sci. Food Agric. 37: 231-238.

Malley, D.F., P.D. Martin, and E. Ben-Dor. 2004. Application in analysis of soils. Chapter 26, p. 729-784. In C.A. Roberts, J. Workman, Jr., and J.B. Reeves III (eds). Near-Infrared Spectroscopy in Agriculture. Agronomy 44. American Society of Agronomy, Inc., Crop Science Society of America, Inc., Soil Science Society of America, Inc. Publishers, Madison WI.

Malley, D.F., C. McClure, P.D. Martin, N. Firlotte, G. Goldsborough and M. Sheppard. 2002. Evaluation of near-infrared spectroscopy as a rapid method for estimating the carbon stored per unit area in a wetland. Final Report to the Manitoba Climate Change Action Fund on Project #15, December, 49 pp.

Malley, D.F., C. McClure, P.D. Martin, G. Goldsborough, and M. Sheppard. 2004. Carbon stored per unit area and moisture in a Canadian wetland determined by NIRS. p. 757-762. A.M.C. Davies and A. Garrido-Varo (eds). Near Infrared Spectroscopy: Proceedings of the 11th International Conference, NIR Publications, Chichester, West Sussex UK

McTiernan, K. B., M.H.Garnett, D. Maurquoy, P. Ineson, and M.-M. Couteaux. 1998. Use of near-infrared reflectance spectroscopy (NIRS) in palaeoecological studies of peat. The Holocene 8: 729-740.

Nilsson, M., T. Korsman, A. Nordgren, C. Palmborg, I. Renberg, and J. Ohman. 1993. NIR spectroscopy used in the microbiological and environmental sciences. p 229‑234. In K.I. Hildrum, T. Isaksson, T. Naes, and A. Tandberg (eds.) Near Infra‑red Spectroscopy: Bridging the Gap between Data Analysis and NIR Applications. Ellis Horwood, New York.

Project (September 2006 - December 2007)

Photo of wetlandsEastside Boreal Peatlands Carbon Monitoring

Funded by the Province of Manitoba Climate Change Action Fund as Project 05-010

Purpose of Project

This project is envisioned as the first component of a larger, multi-year project whose goal is the establishment of boreal forest/peatlands research sites in the pristine and largely unstudied East Side of Lake Winnipeg for the purposes of:

The project will collect cores from representative peatland habitats in the Poplar River Traditional Resource Area that will be analyzed for moisture and carbon content with NIRS.

Poplar River First Nation completed a lands management plan that documents the ecological integrity of the Poplar River Traditional Resource Area and recognizes that the territory is an excellent situation for natural science research on ecological issues such as climate change and biodiversity. The First Nation foresees and welcomes cooperative research and monitoring studies as part of land management plan implementation.

The overall project also has educational, capacity-building, technology transfer, and knowledge transfer goals whereby methods, practices, data, and information are shared among all partners, with particular emphasis on training for youth and students and the integration of traditional ecological knowledge and western scientific approaches.

Partners/Collaborators

Project Proponent and Manager:
Poplar River First Nation
Contact Person: Ray Rabliauskus, Lands Manager
Address: Band Office
Town/City: Poplar River, Manitoba
Postal Code: R0B 0Z0
Email: rayrab@poplarriverfirstnation.ca
http://www.poplarriverfirstnation.ca/

Dr. Jim McLaughlin, Forest Soil Research Scientist
Ontario Forest Research Institute
Ontario Ministry of Natural Resources
1235 Queen Street East
Sault Ste. Marie, Ontario P6A 2E5.
Email: jim.mclaughlin@ontario.ca

Project (April - December 2002)

Evaluation of near-infrared spectroscopy as a rapid method for estimating the carbon stored per unit area in a wetland.

Funded by the Province of Manitoba Climate Change Action Fund as Project 03-05-02 CCAF 15.

Purpose of Project

This project involved the collection of cores from three representative biological communities in Delta Marsh, MB, down to the substrate below the wetland. The amount of total carbon per unit area of wetland surface was estimated using NIRS.

Partners/Collaborators

Dr. Gordon Goldsborough,
Director, University Field Station (Delta Marsh), University of Manitoba
Winnipeg, Manitoba Canada R3T 2N2
Tel: 204-474-7469 Fax: 204-474-7650
E-mail: ggoldsb@cc.umanitoba.ca

Marsha I. Sheppard Ph.D., P. Geo.
ECOMatters Inc.
Suite 105, W.B. Lewis Business Centre
24 Aberdeen Ave., Pinawa, MB, Canada, R0E 1L0
Tel: 204-753-2747
E-mail: sheppardm@ecomatters.com

Report

Malley, D.F., C. McClure, P.D. Martin, N. Firlotte, G. Goldsborough and M. Sheppard. 2002. Evaluation of near-infrared spectroscopy as a rapid method for estimating the carbon stored per unit area in a wetland. Final Report to the Manitoba Climate Change Action Fund on Project #15, December, 49 pp. (Download pdf)

Executive Summary

The purpose of this study was to develop and evaluate a rapid, cost-effective method using near-infrared spectroscopy (NIRS) for estimating the quantity of total C per unit area (g cm-2) in a lacustrine wetland. Three representative sites in Delta Marsh, on the shore of Lake Manitoba, Manitoba were sampled, Crescent Pond, a small isolated, sheltered, clear-water pond; Eaglenest, a larger bay unconnected to Lake Manitoba; and Cadham Bay, a large, deeper, turbid-water bay connected to the lake. Duplicate cores were collected at each site for a total of 6 cores. Cores ranged in length from 52 to 75 cm long and, at least in Cadham Bay, are believed to contain most of the carbon accumulated in the 2500 y geological history of the marsh. The 1-cm thick sections of the cores, comprising the samples in the study, were scanned with two NIR instruments with differing optical systems, data collection time, wavelength range, and field-portability, the Foss NIRSystems Inc. model 6500 visible/NIR scanning spectrophotometer and the Zeiss Corona spectrometer. Samples were scanned field-moist ("as is") and dry. Principal component analysis of the spectral data indicated qualitative differences in the samples among sites that are postulated to be due to variation in the influences of terrestriality vs limnology on the sites.

Calibrations were developed for moisture between the spectral data and gravimetric moisture determined in the samples and for C in the dried and field-moist samples. The NIR-predicted values for moisture agreed 93 and 94% with moisture determined by oven drying the samples for the 6500 and Corona instruments, respectively. These calibrations were judged using statistical criteria to be "excellent". The NIR-predicted values for C in the dried samples agreed 95 and 90% with the C values obtained by combustion for the 6500 and Corona instruments, respectively. For field-moist samples, the NIR-predicted values for C agreed 86 and 87% with the C contents calculated on a wet weight basis from the combustion reference data for the 6500 and Corona, respectively. These calibrations are judged to be "successful" to "excellent".

The total C contained in the six cores determined using the 6500 was 2.51, 2.79, 2.99, 2.49, 3.24, and 2.87 g cm-2. Variability in core length affected the total C. Total C calculated for slices 2 to 51 cm, common to all cores, was 2.42, 2.43, and 2.06 g cm-2 for Crescent Pond, Eaglenest and Cadham Bay, respectively. Crescent Pond and Eaglenest were highly similar in C profiles; Cadham Bay contained lower C content above 50 cm. The results for C per unit area for each core were very similar between the 6500 and Corona NIR instruments. The coefficient of variability (deviation as a % of the mean) for total C between the two instruments for the six cores varied from 0.05 to 2.74 %.

Near-infrared spectroscopy is a feasible method for the determination of C inventories in wetlands when combined with effective sampling of the full depth of the organic C layer, appropriate sampling of spatial variability in the depth of the organic layer within representative habitats of the wetland, and measurement of areal extent of the representative habitats. It is expected from the literature that the technique can be utilized in peatlands as well as in lacustrine wetlands. Field-portability such as available in the Zeiss Corona can further reduce cost, time and effort, and increase efficiency.